Name | 2,4,6-Triphenylpyrylium tetrafluoroborate |
Synonyms | 2,4,6-Triphenylpyrylium tetrafluoroborate 2,4,6-triphenyl-pyryliutetrafluoroborate(1-) Pyrylium, 2,4,6-triphenyl-, tetrafluoroborate(1-) 2 4 6-TRIPHENYLPYRYLIUM TETRAFLUORO-Pyrylium tetrafluoroborate |
CAS | 448-61-3 |
EINECS | 207-186-4 |
InChIKey | VQYPWMWEJGDSTF-UHFFFAOYSA-N |
Molecular Formula | C23H17BF4O |
Molar Mass | 396.20 |
Melting Point | 250-251 °C(lit.) |
Water Solubility | Insoluble in water, ethyl alcohol, diethyl ether. Soluble in trifluroacetic acid. |
Storage Condition | Store below +30°C. |
MDL | MFCD00012001 |
Use | Application 2,4, 6-triphenylpyran boron tetrafluoride salt is an organic intermediate, can be used for the preparation of silk ring aromatic hydrocarbon, silk ring aromatic hydrocarbon has outstanding photoelectric properties, in the organic chemical industry plays an increasingly important role. |
Hazard Symbols | Xn - Harmful |
Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S22 - Do not breathe dust. S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
WGK Germany | 3 |
RTECS | UZ1370000 |
HS Code | 29329900 |
Downstream Products | 2,4,6-TRIPHENYLPYRIDINE |
sensitivity | Moisture Sensitive |
BRN | 3586533 |
2,4, 6-triphenylpyran tetrafluoroate can be prepared by one-step reaction of acetophenone and benzaldehyde.
under the protection of nitrogen, the mixture of acetophenone (24.0g,0.2mol), benzaldehyde (10.6g,01mol) and BF3 · Et2O(3.0mL) was heated to 100 ℃ for 2 hours. Cool to room temperature, add appropriate amount of ether, precipitate, filter and wash with ether, dry to obtain yellow crystals with 65% yield.